Brown carbon: A significant atmospheric absorber of solar radiation?

Citation:
Feng, Y, Ramanathan V, Kotamarthi VR.  2013.  Brown carbon: A significant atmospheric absorber of solar radiation? Atmospheric Chemistry and Physics. 13:8607-8621.

Date Published:

9/2013

Keywords:

aeronet, Aerosols, black, carbon, chemical-transport model, climate, light-absorption, optical-properties, organic-carbon, particulate matter, spectral dependence

Abstract:

Several recent observational studies have shown organic carbon aerosols to be a significant source of absorption of solar radiation. The absorbing part of organic aerosols is referred to as "brown" carbon (BrC). Using a global chemical transport model and a radiative transfer model, we estimate for the first time the enhanced absorption of solar radiation due to BrC in a global model. The simulated wavelength dependence of aerosol absorption, as measured by the absorption Angstrolm exponent (AAE), increases from 0.9 for non-absorbing organic carbon to 1.2 (1.0) for strongly (moderately) absorbing BrC. The calculated AAE for the strongly absorbing BrC agrees with AERONET spectral observations at 440-870 nm over most regions but overpredicts for the biomass burning-dominated South America and southern Africa, in which the inclusion of moderately absorbing BrC has better agreement. The resulting aerosol absorption optical depth increases by 18% (3 %) at 550 nm and 56% (38 %) at 380 nm for strongly (moderately) absorbing BrC. The global simulations suggest that the strongly absorbing BrC contributes up to +0.25 Wm(-2) or 19% of the absorption by anthropogenic aerosols, while 72% is attributed to black carbon, and 9% is due to sulfate and non-absorbing organic aerosols coated on black carbon. Like black carbon, the absorption of BrC (moderately to strongly) inserts a warming effect at the top of the atmosphere (TOA) (0.04 to 0.11 Wm(-2)), while the effect at the surface is a reduction (-0.06 to -0.14 Wm(-2)). Inclusion of the strongly absorption of BrC in our model causes the direct radiative forcing (global mean) of organic carbon aerosols at the TOA to change from cooling (-0.08 Wm(-2)) to warming (+0.025 Wm(-2)). Over source regions and above clouds, the absorption of BrC is higher and thus can play an important role in photochemistry and the hydrologic cycle.

Notes:

n/a

Website

DOI:

10.5194/acp-13-8607-2013