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Sutton, AJ, Feely RA, Maenner-Jones S, Musielwicz S, Osborne J, Dietrich C, Monacci N, Cross J, Bott R, Kozyr A, Andersson AJ, Bates NR, Cai WJ, Cronin MF, DeCarlo EH, Hales B, Howden SD, Lee CM, Manzello DP, McPhaden MJ, Melendez M, Mickett JB, Newton JA, Noakes SE, Noh JH, Olafsdottir SR, Salisbury JE, Send U, Trull TW, Vandemark DC, Weller RA.  2019.  Autonomous seawater pCO(2) and pH time series from 40 surface buoys and the emergence of anthropogenic trends. Earth System Science Data. 11:421-439.   10.5194/essd-11-421-2019   AbstractWebsite

Ship-based time series, some now approaching over 3 decades long, are critical climate records that have dramatically improved our ability to characterize natural and anthropogenic drivers of ocean carbon dioxide (CO2) uptake and biogeochemical processes. Advancements in autonomous marine carbon sensors and technologies over the last 2 decades have led to the expansion of observations at fixed time series sites, thereby improving the capability of characterizing sub-seasonal variability in the ocean. Here, we present a data product of 40 individual autonomous moored surface ocean pCO(2) (partial pressure of CO2) time series established between 2004 and 2013, 17 also include autonomous pH measurements. These time series characterize a wide range of surface ocean carbonate conditions in different oceanic (17 sites), coastal (13 sites), and coral reef (10 sites) regimes. A time of trend emergence (ToE) methodology applied to the time series that exhibit well-constrained daily to interannual variability and an estimate of decadal variability indicates that the length of sustained observations necessary to detect statistically significant anthropogenic trends varies by marine environment. The ToE estimates for seawater pCO(2) and pH range from 8 to 15 years at the open ocean sites, 16 to 41 years at the coastal sites, and 9 to 22 years at the coral reef sites. Only two open ocean pCO(2) time series, Woods Hole Oceanographic Institution Hawaii Ocean Time-series Station (WHOTS) in the subtropical North Pacific and Stratus in the South Pacific gyre, have been deployed longer than the estimated trend detection time and, for these, deseasoned monthly means show estimated anthropogenic trends of 1.9 +/- 0.3 and 1.6 +/- 0.3 mu atm yr(-1), respectively. In the future, it is possible that updates to this product will allow for the estimation of anthropogenic trends at more sites; however, the product currently provides a valuable tool in an accessible format for evaluating climatology and natural variability of surface ocean carbonate chemistry in a variety of regions. Data are available at https.//doi. org/10.7289/V5DB8043 and https.// (Sutton et al., 2018).

Ganachaud, A, Cravatte S, Sprintall J, Germineaud C, Alberty M, Jeandel C, Eldin G, Metzl N, Bonnet S, Benavides M, Heimburger LE, Lefevre J, Michael S, Resing J, Queroue F, Sarthou G, Rodier M, Berthelot H, Baurand F, Grelet J, Hasegawa T, Kessler W, Kilepak M, Lacan F, Privat E, Send U, Van Beek P, Souhaut M, Sonke JE.  2017.  The Solomon Sea: its circulation, chemistry, geochemistry and biology explored during two oceanographic cruises. Elementa-Science of the Anthropocene. 5   10.1525/elementa.221   AbstractWebsite

The semi-enclosed Solomon Sea in the southwestern tropical Pacific is on the pathway of a major oceanic circuit connecting the subtropics to the equator via energetic western boundary currents. Waters transiting through this area replenish the Pacific Warm Pool and ultimately feed the equatorial current system, in particular the equatorial undercurrent. In addition to dynamical transformations, water masses undergo nutrient and micronutrient enrichment when coming in contact with the coasts, impacting the productivity of the downstream equatorial region. Broadscale observing systems are not well suited for describing the fine-scale currents and water masses properties in the Solomon Sea, leaving it relatively unexplored. Two multidisciplinary oceanographic cruises were conducted in the Solomon Sea region, the first in July-August 2012 and the second in March 2014, by investigators from France and the United States. The experimental approach combined physical, chemical, geochemical and biogeochemical analyses, providing access to a wide range of space and time scales of the circulation. This collection of data allows describing the fine-scale structure of the currents and the water properties, transformations and mixing from the surface to the sill depth in the Solomon Sea and in the straits connecting it to the equator. Ocean-margin exchanges were documented through a comprehensive sampling of trace elements and isotopes as efficient tracers of natural fertilization processes. As air chemistry is largely impacted by the regional volcanic plumes, rainwater pH was also sampled. Dinitrogen fixation rates were measured and found to be among the highest in the global ocean, highlighting this region as a hot spot of nitrogen fixation. This study provides an overview of the climatic context during both cruises and the physical circulation and water masses properties. It provides a comprehensive description of all measurements made onboard, and presents preliminary results, aiming to serve as a reference for further physical, geochemical and biogeochemical studies.