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Hamme, RC, Emerson SR, Severinghaus JP, Long MC, Yashayaev I.  2017.  Using noble gas measurements to derive air-sea process information and predict physical gas saturations. Geophysical Research Letters. 44:9901-9909.   10.1002/2017gl075123   AbstractWebsite

Dissolved gas distributions are important because they influence oceanic habitats and Earth's climate, yet competing controls by biology and physics make gas distributions challenging to predict. Bubble-mediated gas exchange, temperature change, and varying atmospheric pressure all push gases away from equilibrium. Here we use new noble gas measurements from the Labrador Sea to demonstrate a technique to quantify physical processes. Our analysis shows that water-mass formation can be represented by a quasi steady state in which bubble fluxes and cooling push gases away from equilibrium balanced by diffusive gas exchange forcing gases toward equilibrium. We quantify the rates of these physical processes from our measurements, allowing direct comparison to gas exchange parameterizations, and predict the physically driven saturation of other gases. This technique produces predictions that reasonably match N-2/Ar observations and demonstrates that physical processes should force SF6 to be approximate to 6% more supersaturated than CFC-11 and CFC-12, impacting ventilation age calculations. Plain Language Summary Gases dissolved in the ocean are important because they influence oceanic habitats and Earth's climate. Physics and biology combine to control the amounts of gases like carbon dioxide, oxygen, and nitrogen in the ocean. Our research seeks to disentangle and quantify the competing effects of physics and biology on dissolved gases. We present very precise measurements of dissolved noble gas concentrations (neon, argon, and krypton) in the Labrador Sea, one of the few places on Earth where the surface and deep ocean communicate with each other. Because noble gases have no biological function, responding only to physical processes in the ocean, we use these measurements to discover the amounts of physical processes that affect gases during the winter at this site, like rapid cooling of the water or bubbles injected by breaking waves. From these amounts of physical processes, we calculate the concentrations of nitrogen and chlorofluorocarbons if only physical processes affected these gases. Our work will allow oceanographers to better estimate the rate that bioavailable nutrients are being removed from the ocean (a process that biologically creates nitrogen gas) and to better determine how the ocean moves from observations of changing chlorofluorocarbons in the ocean.

Buizert, C, Cuffey KM, Severinghaus JP, Baggenstos D, Fudge TJ, Steig EJ, Markle BR, Winstrup M, Rhodes RH, Brook EJ, Sowers TA, Clow GD, Cheng H, Edwards RL, Sigl M, McConnell JR, Taylor KC.  2015.  The WAIS Divide deep ice core WD2014 chronology - Part 1: Methane synchronization (68-31 kaBP) and the gas age-ice age difference. Climate of the Past. 11:153-173.   10.5194/cp-11-153-2015   AbstractWebsite

The West Antarctic Ice Sheet Divide (WAIS Divide, WD) ice core is a newly drilled, high-accumulation deep ice core that provides Antarctic climate records of the past similar to 68 ka at unprecedented temporal resolution. The upper 2850m (back to 31.2 ka BP) have been dated using annual-layer counting. Here we present a chronology for the deep part of the core (67.8-31.2 ka BP), which is based on stratigraphic matching to annual-layer-counted Greenland ice cores using globally well-mixed atmospheric methane. We calculate the WD gas age-ice age difference (Delta age) using a combination of firn densification modeling, ice-flow modeling, and a data set of delta N-15-N-2, a proxy for past firn column thickness. The largest Delta age at WD occurs during the Last Glacial Maximum, and is 525 +/- 120 years. Internally consistent solutions can be found only when assuming little to no influence of impurity content on densification rates, contrary to a recently proposed hypothesis. We synchronize the WD chronology to a linearly scaled version of the layer-counted Greenland Ice Core Chronology (GICC05), which brings the age of Dansgaard-Oeschger (DO) events into agreement with the U = Th absolutely dated Hulu Cave speleothem record. The small Delta age at WD provides valuable opportunities to investigate the timing of atmospheric greenhouse gas variations relative to Antarctic climate, as well as the interhemispheric phasing of the "bipolar seesaw".

Wagner, TJW, Dell RW, Eisenman I, Keeling RF, Padman L, Severinghaus JP.  2018.  Wave inhibition by sea ice enables trans-Atlantic ice rafting of debris during Heinrich events. Earth and Planetary Science Letters. 495:157-163.   10.1016/j.epsl.2018.05.006   AbstractWebsite

The last glacial period was punctuated by episodes of massive iceberg calving from the Laurentide Ice Sheet, called Heinrich events, which are identified by layers of ice-rafted debris (IRD) in ocean sediment cores from the North Atlantic. The thickness of these IRD layers declines more gradually with distance from the iceberg sources than would be expected based on present-day iceberg drift and decay. Here we model icebergs as passive Lagrangian particles driven by ocean currents, winds, and sea surface temperatures. The icebergs are released in a comprehensive climate model simulation of the last glacial maximum (LGM), as well as a simulation of the modern climate. The two simulated climates result in qualitatively similar distributions of iceberg meltwater and hence debris, with the colder temperatures of the LGM having only a relatively small effect on meltwater spread. In both scenarios, meltwater flux falls off rapidly with zonal distance from the source, in contrast with the more uniform spread of IRD in sediment cores. To address this discrepancy, we propose a physical mechanism that could have prolonged the lifetime of icebergs during Heinrich events. The mechanism involves a surface layer of cold and fresh meltwater formed from, and retained around, large densely packed armadas of icebergs. This leads to wintertime sea ice formation even in relatively low latitudes. The sea ice in turn shields the icebergs from wave erosion, which is the main source of iceberg ablation. We find that sea ice could plausibly have formed around the icebergs during four months each winter. Allowing for four months of sea ice in the model results in a simulated IRD distribution which approximately agrees with the distribution of IRD in sediment cores. (C) 2018 Elsevier B.V. All rights reserved.

Fischer, H, Severinghaus J, Brook E, Wolff E, Albert M, Alemany O, Arthern R, Bentley C, Blankenship D, Chappellaz J, Creyts T, Dahl-Jensen D, Dinn M, Frezzotti M, Fujita S, Gallee H, Hindmarsh R, Hudspeth D, Jugie G, Kawamura K, Lipenkov V, Miller H, Mulvaney R, Parrenin F, Pattyn F, Ritz C, Schwander J, Steinhage D, van Ommen T, Wilhelms F.  2013.  Where to find 1.5 million yr old ice for the IPICS "Oldest-Ice" ice core. Climate of the Past. 9:2489-2505.   10.5194/cp-9-2489-2013   AbstractWebsite

The recovery of a 1.5 million yr long ice core from Antarctica represents a keystone of our understanding of Quaternary climate, the progression of glaciation over this time period and the role of greenhouse gas cycles in this progression. Here we tackle the question of where such ice may still be found in the Antarctic ice sheet. We can show that such old ice is most likely to exist in the plateau area of the East Antarctic ice sheet (EAIS) without stratigraphic disturbance and should be able to be recovered after careful pre-site selection studies. Based on a simple ice and heat flow model and glaciological observations, we conclude that positions in the vicinity of major domes and saddle position on the East Antarctic Plateau will most likely have such old ice in store and represent the best study areas for dedicated reconnaissance studies in the near future. In contrast to previous ice core drill site selections, however, we strongly suggest significantly reduced ice thickness to avoid bottom melting. For example for the geothermal heat flux and accumulation conditions at Dome C, an ice thickness lower than but close to about 2500m would be required to find 1.5 Myr old ice (i.e., more than 700m less than at the current EPICA Dome C drill site). Within this constraint, the resolution of an Oldest-Ice record and the distance of such old ice to the bedrock should be maximized to avoid ice flow disturbances, for example, by finding locations with minimum geothermal heat flux. As the geothermal heat flux is largely unknown for the EAIS, this parameter has to be carefully determined beforehand. In addition, detailed bedrock topography and ice flow history has to be reconstructed for candidates of an Oldest-Ice ice coring site. Finally, we argue strongly for rapid access drilling before any full, deep ice coring activity commences to bring datable samples to the surface and to allow an age check of the oldest ice.