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Petrenko, VV, Severinghaus JP, Brook EJ, Reeh N, Schaefer H.  2006.  Gas records from the West Greenland ice margin covering the Last Glacial Termination: a horizontal ice core. Quaternary Science Reviews. 25:865-875.   10.1016/j.quascirev.2005.09.005   AbstractWebsite

Certain sites along ice sheet margins provide an easily accessible and almost unlimited supply of ancient ice at the surface. Measurements of gases in trapped air from ice outcropping at Pakitsoq, West Greenland, demonstrate that ancient air is mostly well preserved. No alterations in delta O-18(atm) and delta N-15 of N-2 are apparent, and alterations in methane are found in only a few ice sections. Using measurements of these gases, we have unambiguously identified a stratigraphic section containing ice from the end of last glacial period as well as Bolling-Allerod, Younger Dryas and Preboreal intervals. Extensive sections of ice from the Holocene and most ages within the last glacial period are probably also present. Very accurate dating has been possible in the ice section containing the Younger Dryas-Preboreal abrupt climate transition signal. The ice at Pakitsoq is folded and non-uniformly thinned, with many cross-cutting bands of bubble-free ice and dust. The cross-cutting features are associated with anomalies in both the gas and the ice records. With careful sampling to avoid these, the ice at Pakitsoq is suitable for recovery of large-volume samples of the ancient atmosphere for analysis of trace constituents such as (CH4)-C-14. (c) 2005 Elsevier Ltd. All rights reserved.

Buizert, C, Martinerie P, Petrenko VV, Severinghaus JP, Trudinger CM, Witrant E, Rosen JL, Orsi AJ, Rubino M, Etheridge DM, Steele LP, Hogan C, Laube JC, Sturges WT, Levchenko VA, Smith AM, Levin I, Conway TJ, Dlugokencky EJ, Lang PM, Kawamura K, Jenk TM, White JWC, Sowers T, Schwander J, Blunier T.  2012.  Gas transport in firn: multiple-tracer characterisation and model intercomparison for NEEM, Northern Greenland. Atmospheric Chemistry and Physics. 12:4259-4277.   10.5194/acp-12-4259-2012   AbstractWebsite

Air was sampled from the porous firn layer at the NEEM site in Northern Greenland. We use an ensemble of ten reference tracers of known atmospheric history to characterise the transport properties of the site. By analysing uncertainties in both data and the reference gas atmospheric histories, we can objectively assign weights to each of the gases used for the depth-diffusivity reconstruction. We define an objective root mean square criterion that is minimised in the model tuning procedure. Each tracer constrains the firn profile differently through its unique atmospheric history and free air diffusivity, making our multiple-tracer characterisation method a clear improvement over the commonly used single-tracer tuning. Six firn air transport models are tuned to the NEEM site; all models successfully reproduce the data within a 1 sigma Gaussian distribution. A comparison between two replicate boreholes drilled 64 m apart shows differences in measured mixing ratio profiles that exceed the experimental error. We find evidence that diffusivity does not vanish completely in the lock-in zone, as is commonly assumed. The ice age- gas age difference (Delta age) at the firn-ice transition is calculated to be 182(-9)(+3) yr. We further present the first intercomparison study of firn air models, where we introduce diagnostic scenarios designed to probe specific aspects of the model physics. Our results show that there are major differences in the way the models handle advective transport. Furthermore, diffusive fractionation of isotopes in the firn is poorly constrained by the models, which has consequences for attempts to reconstruct the isotopic composition of trace gases back in time using firn air and ice core records.

Alley, RB, Lynch-Stieglitz J, Severinghaus JP.  1999.  Global climate change. Proceedings of the National Academy of Sciences of the United States of America. 96:9987-9988.   10.1073/pnas.96.18.9987   AbstractWebsite

Most of the last 100,000 years or longer has been characterized by large, abrupt, regional-to-global climate changes. Agriculture and industry have developed during anomalously stable climatic conditions, New, high-resolution analyses of sediment cores using multiproxy and physically based transfer functions allow increasingly confident interpretation of these past changes as having been caused by "band jumps" between modes of operation of the climate system. Recurrence of such band jumps is possible and might be affected by human activities.

Buizert, C, Gkinis V, Severinghaus JP, He F, Lecavalier BS, Kindler P, Leuenberger M, Carlson AE, Vinther B, Masson-Delmotte V, White JWC, Liu ZY, Otto-Bliesner B, Brook EJ.  2014.  Greenland temperature response to climate forcing during the last deglaciation. Science. 345:1177-1180.   10.1126/science.1254961   AbstractWebsite

Greenland ice core water isotopic composition (delta O-18) provides detailed evidence for abrupt climate changes but is by itself insufficient for quantitative reconstruction of past temperatures and their spatial patterns. We investigate Greenland temperature evolution during the last deglaciation using independent reconstructions from three ice cores and simulations with a coupled ocean-atmosphere climate model. Contrary to the traditional delta O-18 interpretation, the Younger Dryas period was 4.5 degrees +/- 2 degrees C warmer than the Oldest Dryas, due to increased carbon dioxide forcing and summer insolation. The magnitude of abrupt temperature changes is larger in central Greenland (9 degrees to 14 degrees C) than in the northwest (5 degrees to 9 degrees C), fingerprinting a North Atlantic origin. Simulated changes in temperature seasonality closely track changes in the Atlantic overturning strength and support the hypothesis that abrupt climate change is mostly a winter phenomenon.