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Cabral, RA, Jackson MG, Rose-Koga EF, Koga KT, Whitehouse MJ, Antonelli MA, Farquhar J, Day JMD, Hauri EH.  2013.  Anomalous sulphur isotopes in plume lavas reveal deep mantle storage of Archaean crust. Nature. 496:490-+.   10.1038/nature12020   AbstractWebsite

Basaltic lavas erupted at some oceanic intraplate hotspot volcanoes are thought to sample ancient subducted crustal materials(1,2). However, the residence time of these subducted materials in the mantle is uncertain and model-dependent(3), and compelling evidence for their return to the surface in regions of mantle upwelling beneath hotspots is lacking. Here we report anomalous sulphur isotope signatures indicating mass-independent fractionation (MIF) in olivine-hosted sulphides from 20-million-year-old ocean island basalts from Mangaia, Cook Islands (Polynesia), which have been suggested to sample recycled oceanic crust(3,4). Terrestrial MIF sulphur isotope signatures (in which the amount of fractionation does not scale in proportion with the difference in the masses of the isotopes) were generated exclusively through atmospheric photochemical reactions until about 2.45 billion years ago(5-7). Therefore, the discovery of MIF sulphur in these young plume lavas suggests that sulphur-probably derived from hydrothermally altered oceanic crust-was subducted into the mantle before 2.45 billion years ago and recycled into the mantle source of Mangaia lavas. These new data provide evidence for ancient materials, with negative Delta S-33 values, in the mantle source for Mangaia lavas. Our data also complement evidence for recycling of the sulphur content of ancient sedimentary materials to the subcontinental lithospheric mantle that has been identified in diamond-hosted sulphide inclusions(8,9). This Archaean age for recycled oceanic crust also provides key constraints on the length of time that subducted crustal material can survive in the mantle, and on the timescales of mantle convection from subduction to upwelling beneath hotspots.

Day, JMD, Taylor LA, Floss C, McSween HY.  2006.  Petrology and chemistry of MIL 03346 and its significance in understanding the petrogenesis of nakhlites on Mars. Meteoritics & Planetary Science. 41:581-606. AbstractWebsite

Antarctic meteorite Miller Range (MIL) 03346 is a nakhlite composed of 79% clinopyroxene, similar to 1% olivine, and 20% vitrophyric intercumulus material. We have performed a petrological and geochemical study of MIL 03346, demonstrating a petrogenetic history similar to previously discovered naklilites. Quantitative textural study of MIL 03346 indicates long (> 1 x 10(1) yr) residence times for the Cumulus augite, whereas the skeletal Fe-Ti oxide, fayalite, and sulfide in the vitrophyric intercumulus matrix suggest rapid cooling, probably as a lava flow. From the relatively high forsterite contents of olivine (up to Fo(43)) compared with other nakhlites and compositions of augite cores (Wo(38-42)En(35-40)Fs(22-28)) and their hedenbergite rims, we suggest that MIL 03346 is part of the same or a similar Martian Cumulate-rich lava flow as other nakhlites. However, MIL 03346 has experienced less equilibration and faster cooling than other nakhlites discovered to date. Calculated trace element concentrations based upon modal abundances of MIL 03346 and its constituent minerals are identical to whole rock trace element abundances. Parental melts for augite have REE patterns that are approximately parallel with whole rock and intercumulus melt using experimentally defined partition coefficients. This parallelism reflects closed-system crystallization for MIL 03346, where the only significant petrogenetic process between formation of augite and eruption and emplacement of the nakhlite flow has been fractional crystallization. A model for the petrogenesis of MIL 03346 and the naklilites (Nakhla, Governador Valadares, Lafayette, Yamato-000593, Northwest Africa (NWA) 817, NWA 998) Would include: 1) partial melting and ascent of melt generated from a long-term LREE depleted mantle Source, 2) crystallization of cumulus augite (+/- olivine, +/- magnetite) in a shallow-level Martian magma chamber, 3) eruption of the crystal-laden naklilite magma onto the surface of Mars, 4) cooling, crystal settling, overgrowth, and partial equilibration to different extents within the flow, 5) secondary alteration through hydrothermal processes, possibly immediately succeeding or during emplacement of the flow. This model might apply to single-or multiple-flow models for the nakhlites. Ultimately, MIL 03346 and the other nakhlites preserve a record of magmatic processes in volcanic rocks oil Mars with analogous petrogenetic histories to pyroxene-rich terrestrial lava flows and to komatiites.