Publications

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2009
Stith, JL, Ramanathan V, Cooper WA, Roberts GC, DeMott PJ, Carmichael G, Hatch CD, Adhikary B, Twohy CH, Rogers DC, Baumgardner D, Prenni AJ, Campos T, Gao R, Anderson J, Feng Y.  2009.  An overview of aircraft observations from the Pacific Dust Experiment campaign. Journal of Geophysical Research-Atmospheres. 114   10.1029/2008jd010924   AbstractWebsite

Fourteen research flights were conducted in the Pacific Dust Experiment (PACDEX) during April and May 2007 to sample pollution and dust outbreaks from east Asia as they traveled across the northern Pacific Ocean into North America and interacted with maritime storms. Significant concentrations of black carbon (BC, consisting of soot and other light-absorbing particles measured with a soot photometer 2 instrument) and dust were observed both in the west and east Pacific Ocean from Asian plumes of dust and pollution. BC particles were observed through much of the troposphere, but the major finding is that the percentage of these particles compared with the total number of accumulation mode particles increased significantly (by a factor of 2-4) with increasing altitude, with peak values occurring between 5 and 10 km. Dust plumes had only a small impact on total cloud condensation nuclei at the sampling supersaturations but did exhibit high concentrations of ice nuclei (IN). IN concentrations in dust plumes exceeded typical tropospheric values by 4-20 times and were similar to previous studies in the Saharan aerosol layer when differences in the number concentrations of dust are accounted for. Enhanced IN concentrations were found in the upper troposphere off the coast of North America, providing a first direct validation of the transport of high-IN-containing dust layers near the tropopause entering the North American continent from distant sources. A source-specific chemical transport model was used to predict dust and other aerosols during PACDEX. The model was able to predict several features of the in situ observations, including the general altitudes where BC was found and a peak in the ratio of BC to sulfate between 5 and 10 km.

2007
Yum, SS, Roberts G, Kim JH, Song KY, Kim DY.  2007.  Submicron aerosol size distributions and cloud condensation nuclei concentrations measured at Gosan, Korea, during the Atmospheric brown clouds - East Asian Regional Experiment 2005. Journal of Geophysical Research-Atmospheres. 112   10.1029/2006jd008212   AbstractWebsite

Submicron aerosol size distributions, CN and CCN concentrations at a constant supersaturation of 0.6% were measured at a relatively remote coastal site at Gosan in Jeju Island, Korea, during the ABC-EAREX from 11 March to 8 April 2005. The average CN concentrations were 6088 +/- 3988, 5231 +/- 2454 and 3513 +/- 1790 cm(-3), respectively, for the three major air mass types classified by their origins. The corresponding CCN concentrations were 2393 +/- 1156, 2897 +/- 1226 and 1843 +/- 585 cm(-3). The type III air mass was the closest to maritime origins, but these lowest concentrations at Gosan were an order of magnitude higher than those of clean marine boundary layer, indicating that regardless of air mass designation springtime submicron aerosols at Gosan were under steady continental influences. Distinct new particle formation and growth events occurred on 6 d, when clear sky weather conditions prevailed that brought air from northern China, Mongolia or Russia by anticyclonic circulations. Simultaneous occurrence of these events at a western coastal site in the Korean Peninsula 350 km north of Gosan suggests that these events were not local but at least regional-scale events. CCN concentrations were predicted with the aerosol size distributions and the assumption of particles being composed of ( NH(4))(2)SO(4). The predicted to measured CCN concentration ratio was 1.27 +/- 0.29 and the r(2) was 0.77 for the whole measurement period. The type I air mass that has the most continental influences showed a slight tendency to overpredict CCN concentrations but the good agreement overall suggests that springtime Gosan aerosols act almost like ammonium sulfate as far as CCN activity is concerned, almost regardless of air mass origin.

Hadley, OL, Ramanathan V, Carmichael GR, Tang Y, Corrigan CE, Roberts GC, Mauger GS.  2007.  Trans-Pacific transport of black carbon and fine aerosols (D < 2.5 ┬Ám) into North America. Journal of Geophysical Research-Atmospheres. 112   10.1029/2006jd007632   AbstractWebsite

[1] This study presents estimates of long-range transport of black carbon (BC) and aerosol fine mass (diameter less than 2.5 mm) across the Pacific Ocean into North America during April 2004. These transport estimates are based on simulations by the Chemical Weather Forecast System (CFORS) model and evaluated across 130 degrees W, (30 degrees N-60 degrees N) from 26 March through 25 April 2004. CFORS calculates BC transport into North America at 25-32 Gg of which over 75% originates from Asia. Modeled fine aerosol mass transport is between 900 and 1100 Gg. The BC transport amounts to about 77% of the published estimates of North American BC emissions. Approximately 78% of the BC and 82% of the fine aerosol mass transport occur in the midtroposphere above 2 km. Given the relatively large magnitude of the estimated BC transport, we undertake a detailed validation of the model simulations of fine aerosol mass and BC over the west coast of North America. In situ aircraft data were available for the month of April 2004 to assess the accuracy of model simulations of aerosols in the lower troposphere. Aircraft data for aerosol mass collected in the eastern Pacific Ocean during April 2004 as part of the Cloud Indirect Forcing Experiment, as well as surface measurements of fine mass and BC at 30 west coast locations, are compared to CFORS predictions. These surface sites are part of the Interagency Monitoring of Protected Visual Environments (IMPROVE) network. Both the aircraft and the IMPROVE data sets reveal similar patterns of good agreement near and above the boundary layer accompanied by large overprediction within the boundary layer. The observational data validate the CFORS simulations of BC and fine aerosol mass above the boundary layer. The near-surface overprediction does not impair the major conclusions of this study regarding long-range aerosol and BC transport, as most of the long-range transport occurs above 2 km. From this we conclude that the transport of BC from Asia and other regions west is a major source of BC at high elevations over North America. The simulated concentrations of BC between 1 and 3 km, as well as the measured BC concentrations over the elevated IMPROVE sites, range from 0.1 to 0.3 mu g/m(3). Direct radiative forcing over North America due to the modeled BC concentration between 1 and 15 km is estimated at an additional 2.04-2.55 W/m(2) absorbed in the atmosphere and a dimming of-1.45 to-1.47 W/m(2) at the surface. The impact of transported BC on the regional radiation budget through direct and indirect effects of the transported BC and other aerosols warrants further study.

2006
Roberts, G, Mauger G, Hadley O, Ramanathan V.  2006.  North American and Asian aerosols over the eastern Pacific Ocean and their role in regulating cloud condensation nuclei. Journal of Geophysical Research-Atmospheres. 111   10.1029/2005jd006661   AbstractWebsite

[ 1] Measurements of aerosol and cloud properties in the Eastern Pacific Ocean were taken during an airborne experiment on the University of Wyoming's King Air during April 2004 as part of the Cloud Indirect Forcing Experiment (CIFEX). We observed a wide variety of aerosols, including those of long-range transport from Asia, clean marine boundary layer, and North American emissions. These aerosols, classified by their size distribution and history, were found in stratified layers between 500 to 7500 m above sea level and thicknesses from 100 to 3000 m. A comparison of the aerosol size distributions to measurements of cloud condensation nuclei (CCN) provides insight to the CCN activity of the different aerosol types. The overall ratio of measured to predicted CCN concentration (NCCN) is 0.56 +/- 0.41 with a relationship of N-CCN,N- measured = N-CCN, predicted(0.846 +/- 0.002) for 23 research flights and 1884 comparisons. Such a relationship does not accurately describe a CCN closure; however, it is consistent with our measurements that high CCN concentrations are more influenced by anthropogenic sources, which are less CCN active. While other CCN closures have obtained results closer to the expected 1: 1 relationship, the different aerosol types ( and presumably differences in aerosol chemistry) are responsible for the discrepancy. The measured N-CCN at 0.3% supersaturation (S-c) ranged from 20 cm(-3) (pristine) to 350 cm(-3) ( anthropogenic) with an average of 106 +/- 54 cm(-3) over the experiment. The inferred supersaturation in the clouds sampled during this experiment is similar to 0.3%. CCN concentrations of cloud-processed aerosol were well predicted using an ammonium sulfate approximation for S-c <= 0.4%. Predicted N-CCN for other aerosol types (i.e., Asian and North American aerosols) were high compared to measured values indicating a less CCN active aerosol. This study highlights the importance of chemical effects on CCN measurements and introduces a CCN activation index as a method of classifying the efficiency of an aerosol to serve as CCN relative to an ammonium sulfate particle. This index ranged from close to unity for cloud processed aerosols to as low as 0.31 for aged aerosols transported from Asia. We also compare the performance of two CCN instruments ( static thermal diffusion chamber and streamwise continuous flow chamber) on a 45 minute level leg where we observe an aged layer and a nucleation event. More than 50% of the aged aerosol served as CCN at 0.2% S-c, primarily owing to their large size, while CCN concentrations during the nucleation event were close to 0 cm(-3). CCN concentrations from both instruments agreed within instrument errors; however, the continuous flow chamber effectively captured the rapid transition in aerosol properties.