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2014
Chin, EJ, Lee C-TA, Barnes JD.  2014.  Thickening, refertilization, and the deep lithosphere filter in continental arcs: Constraints from major and trace elements and oxygen isotopes. Earth and Planetary Science Letters. 397:184-200.   10.1016/j.epsl.2014.04.022   AbstractWebsite

Arc magmatism is a complex process involving generation of primary melts in the mantle wedge and chemical refinement of these melts into differentiated products akin to continental crust. Interaction of magmas (cooling, crystallization and assimilation) with the overlying crust, particularly if it is thick, is one way by which primary basalts are refined into more evolved compositions. Here, we explore the role of the mantle lithosphere as a trap and/or reactive filter of magmas. We use mantle xenoliths from the Sierra Nevada continental arc in California as a probe into sub-Moho processes. Based on clinopyroxene modal abundance and major, minor and moderately incompatible trace element concentrations, the peridotites define a refertilization trend that increases with depth, grading from clinopyroxene-poor ( < 5 % ), undeformed spinel peridotites equilibrated at < 3 GPa ( < 90 km ) to clinopyroxene-rich (10–20%), porphyroclastic garnet peridotites equilibrated between 3 and 3.5 GPa (90–105 km), the latter presumably approaching the top of the subducting slab. The petrology and geochemistry of the xenoliths suggest that the fertile peridotites were originally depleted spinel peridotites, which were subsequently refertilized. Incompatible trace element geochemistry reveals a pervasive cryptic metasomatic overprint in all peridotites, suggesting involvement of small amounts of subduction-derived fluids from the long-lived Farallon plate beneath western North America. However, bulk reconstructed δ O SMOW 18 values of the peridotites, including the most refertilized, fall between 5.4 and 5.9 ‰ , within the natural variability of unmetasomatized mantle ( ∼ 5.5 ± 0.2 ‰ ). Together with Sm, Yb, and Ca compositional data, the oxygen isotope data suggest that the role of slab or sediment melts in refertilizing the peridotites was negligible ( < 5 % in terms of added melt mass). Instead, binary mixing models suggest that many of the Sierran garnet peridotites, particularly those with high clinopyroxene modes, had up to 30% mantle-derived melt added. Our data suggest that refertilization of the deep arc lithosphere, via melt entrapment and clinopyroxene precipitation, may be an important process that modifies the composition of primary arc magmas before they reach the crust and shallowly differentiate. Comparison of our data with a global compilation of arc-related mantle xenoliths suggests that sub-Moho refertilization may be more extensive beneath mature arcs, such as continental arcs, compared to juvenile island arcs, possibly because of the greater thickness of crust and lithosphere beneath mature and island arcs.

Lee, C-TA, Chin EJ.  2014.  Calculating melting temperatures and pressures of peridotite protoliths: Implications for the origin of cratonic mantle. Earth and Planetary Science Letters. 403:273-286.   10.1016/j.epsl.2014.06.048   AbstractWebsite

The old, stable cores of continents – cratons – are underlain by thick and cold mantle keels, composed of melt-depleted and low density peridotite residues. The origins of these thick keels are debated. Were these thick keels formed in situ, by orogenic thickening, or by underplating of buoyant residual mantle? Key to this debate is determining the temperature and pressure at which the protoliths of cratonic peridotites melted (igneous protolith conditions) and comparing to their metamorphic (subsolidus) temperatures and pressures within the keel. This paper presents a method for explicit calculation of the temperatures and pressures at which the peridotite protoliths melted. The approach relies only on the bulk FeO and MgO of residual peridotites. A system of equations consisting of mass balance and new calibrations of Mg peridotite/melt partitioning and melt productivity is then solved simultaneously. The igneous protoliths of abyssal peridotites are found to have melted at effective pressures of 1–2 GPa and temperatures of 1300–1400 °C, within error of the magmatic temperatures and pressures of melt extraction inferred independently from the SiO2 and MgO contents of mid-ocean ridge basalts. Archean cratonic peridotites, after filtering for the secondary effects of refertilization and orthopyroxene-metasomatism, give igneous protolith pressures and temperatures of 1–5 GPa (30–150 km) and 1400–1750 °C, similar to magmatic temperatures and pressures determined for Archean basalts thought to be representative of the thermal state of the Archean ambient mantle. Most importantly, cratonic peridotite protolith pressures and temperatures are shallower and hotter than their subsolidus equilibration pressures (3–7.5 GPa; 90–200 km) and temperatures (900–1300 °C), which reflects the recent thermal state of the cratonic lithosphere. Specifically, for individual samples with both melting and subsolidus thermobarometric constraints, we find that subsolidus pressures are 1–2 GPa (30–60 km) higher than their igneous protolith pressures although some of the deepest samples experienced minor increases in pressure. Collectively, these results support the suggestion that the building blocks of cratons were generated by hot shallow melting with a mantle potential temperature 200–300 °C warmer than the present. This shallowly generated mantle was subsequently thickened during orogenic episodes, culminating in the formation of a thick, stable craton. Whether such thickening has any modern analogs cannot be answered from this work alone.

2012
Chin, EJ, Lee CTA, Luffi P, Tice M.  2012.  Deep Lithospheric Thickening and Refertilization beneath Continental Arcs: Case Study of the P, T and Compositional Evolution of Peridotite Xenoliths from the Sierra Nevada, California. Journal of Petrology. 53:477-511.   10.1093/petrology/egr069   AbstractWebsite

Thickening of arc lithosphere influences the extent of magmatic differentiation and is thereby important for the evolution of juvenile arcs into mature continental crust. Here, we use mantle xenoliths from the late Mesozoic Sierra Nevada continental arc in California (USA) to constrain the pressure, temperature, and compositional evolution of the deep lithosphere beneath a mature arc. These xenoliths consist of spinel peridotites and garnet-bearing spinel peridotites. The former are characterized by coarse-grained protogranular textures having bulk compositions indicative of high-degree melting. The latter are characterized by porphyroclastic textures, garnet coronas around spinels, garnet exsolution lamellae in pyroxenes, and pyroxenes with high-Al cores and low-Al rims. The garnet-bearing spinel peridotites range from depleted to fertile compositions, but the high Cr-numbers [molar Cr/(Cr + Al)] of spinel cores reflect high-degree melting. These observations suggest that the protoliths of the garnet-bearing spinel peridotites were melt-depleted spinel peridotites. Constraints from geothermobarometry and bulk compositions coupled with mantle melting models suggest that the protoliths underwent shallow melt depletion (1-2 GPa, 1300-1400 degrees C), followed by compression, cooling, and final equilibration within the garnet stability field (similar to 3 GPa, < 800 degrees C). The deepest equilibrated samples are the most refertilized, suggesting that refertilization occurred during compression. We interpret this P-T-composition path to reflect progressive thickening of the Sierran arc lithosphere perhaps as a result of magmatic inflation or tectonic thickening. We hypothesize that newly formed arc lithospheric mantle thickens enough to pinch out the asthenospheric wedge, juxtaposing Sierran arc lithosphere against the subducting oceanic plate. This could have terminated arc magmatism and initiated cooling of the deep Sierran lithosphere.

2011
Lee, CTA, Luffi P, Chin EJ.  2011.  Building and Destroying Continental Mantle. Annual Review of Earth and Planetary Sciences, Vol 39. 39:59-90.   10.1146/annurev-earth-040610-133505   AbstractWebsite

Continents, especially their Archean cores, are underlain by thick thermal boundary layers that have been largely isolated from the convecting mantle over billion-year timescales, far exceeding the life span of oceanic thermal boundary layers. This longevity is promoted by the fact that continents are underlain by highly melt-depleted peridotites, which result in a chemically distinct boundary layer that is intrinsically buoyant and strong (owing to dehydration). This chemical boundary layer counteracts the destabilizing effect of the cold thermal state of continents. The compositions of cratonic peridotites require formation at shallower depths than they currently reside, suggesting that the building blocks of continents formed in oceanic or arc environments and became "continental" after significant thickening or underthrusting. Continents are difficult to destroy, but refertilization and rehydration of continental mantle by the passage of melts can nullify the unique stabilizing composition of continents.